Research Article
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Characterisation and Performance of Low-Density Poly Ethylene-Corn Flour Composites

Year 2018, Volume: 2 Issue: 2, 171 - 179, 29.12.2018

Sameer A. Awad , Eman M. Khalaf

https://doi.org/10.29002/asujse.432715
Cited By: 3

Abstract

This study aims to
investigate the effects of corn flour fillers on the
mechanical and thermal properties and surface morphology of low-density polyethylene composites. Low-density polyethylene
(LDPE) and low density polyethylene/corn flour (LDPE/CF) with
different loadings of CF (5%‐20% w/w) were prepared in an
internal mixer type Z-Blade mixer at 190°C and rotor speed of 50 rpm. Dynamic mechanical analysis (DMA), Thermogravimetric
analysis (TGA), differential scanning calorimetry (DSC) and tensile
tests were analysed to investigate thermal
and mechanical properties. Tensile tests displayed an increase in the tensile
strength and modulus with the increase of CF loadings. The results of DMA tests showed significant improvements for the
storage modulus and glass transition temperature, Tg. The
results of TGA indicated that the addition of higher amounts of CF enhanced
thermal stability. 

Keywords

LDPE CF Thermal stability Tensile strength Storage of modules

References

  • [1] M. Alidadi‐Shamsabadi, T. Behzad, R. Bagheri, B. Nari‐Nasrabadi, Preparation and characterization of low‐density polyethylene/thermoplastic starch composites reinforced by cellulose nanofibers, Polym. Compos. 36(12) (2015) 2309-2316.
  • [2] S.A. Awad, E.M. Khalaf, Evaluation of thermal and mechanical properties of Low-Density Poly Ethylene (LDPE)-Corn Flour (CF) composites. Int. Journal ChemTech Research. 10(13) (2017) 230-235.
  • [3] S.A. Awad, E.M. Khalaf, Improvement of the chemical, thermal, mechanical and morphological properties of polyethylene terephthalate–graphene particle composites, Bull. Mater. Sci. 41(3) (2018) 67.
  • [4] P. Blaszczak, W. Brostow, T. Datashvili, H.E.H. Lobland, Rheology of low‐density polyethylene+ Boehmite composites, Polym. Compos. 31(11) (2010) 1909-1913.
  • [5] S.A. Awad, Influence study of (Vitamin C) absorption on the mechanical properties of (Polyethylene terephthalate) drinking bottles. Journal of University of Anbar for Pure Science 5 (2011) 31-36
  • [6] S. Ghafarizadeh, M. Fréchette, E. David, Fabrication and Dielectric, Mechanical, and Thermal Properties of Low-Density Polyethylene (LDPE) Composites Containing Surface-Passivated Silicon (Si/SiO2 Core/Shell Nanoparticles), Polym. Plast. Technol. Eng. 57(4) (2018) 327-334.
  • [7] E.M. Khalaf, S.A. Awad, Improvement of Mechanical and Water Absorbance Properties of Low-Density Polyethylene (LDPE) by using White Kaolin Powder (WK). J. Adv. Chem. Sci. 3(1) (2017) 426-427.
  • [8] M. Goyal, N. Goyal, H. Kaur, A. Gera, K. Minocha, P. Jindal, Fabrication and characterisation of low density polyethylene (LDPE)/multi walled carbon nanotubes (MWCNTs) nano-composites, Perspectives in Science 8 (2016) 403-405.
  • [9] N. Gray, Y. Hamzeh, A. Kaboorani, A. Abdulkhani, Influence of cellulose nanocrystal on strength and properties of low density polyethylene and thermoplastic starch composites, Industrial Crops and Products 115 (2018) 298-305.
  • [10] E. Khalaf, S. Awad, Improvement of Chemical and Thermal Properties of Polyethylene Terephthalate (PET) by Using Multi-Walled Carbon Nanotubes (MWCNTs), International Journal of Materials Science and Applications 5(6) (2016) 297-301.
  • [11] S.A. Awad, E.M. Khalaf, Improvement chemical, thermal, and mechanical properties of Polypropylene by using corn flour, Usak University Journal of Material Sciences 6(1/2) (2017) 15-25.
  • [12] S. Awad, E. Khalaf, Improvement, the Performance of Polyurethane (PUR), Y-290 Resin as Coating of Oil Pipeline by Using Multi-Walled Carbon Nanotubes (MWCNTs), Engineering and Technology Journal 35(8 Part (A) Engineering) (2017) 845-848.
  • [13] A. Luyt, J. Molefi, H. Krump, Thermal, mechanical and electrical properties of copper powder filled low-density and linear low-density polyethylene composites, Polym.Degrad. .Stab.91(7) (2006) 1629-1636.
  • [14] Y.A. Mubarak, R.T. Abdulsamad, Effects of microcrystalline cellulose on the mechanical properties of low-density polyethylene composites, J. Thermoplast. Compos. Mater. (2018) 0892705717753056.
  • [15] C. Reddy, C. Das, Propylene-ethylene copolymer filled nanocomposites: Influence of Zn-ion coating upon nano-SiO2 on structural, thermal, and dynamic mechanical properties, Polym. Plast.Technol. Eng. 45(7) (2006) 815-820.
  • [16] P. Roy, P. Surekha, C. Rajagopal, S. Chatterjee, V. Choudhary, Accelerated aging of LDPE films containing cobalt complexes as prooxidants, Polym. Degrad. Stab. 91(8) (2006) 1791-1799.
  • [17] K. Şirin, M. Balcan, F. Doğan. The influence of filler component on mechanical properties and thermal analysis of PP-LDPE and PP-LDPE/DAP ternary composites, Polypropylene, InTech, 2012.
  • [18] Z. Wang, M. Lu, H.-L. Li, X.-Y. Guo, SWNTs–polystyrene composites preparations and electrical properties research, Mater. Chem. Phys. 100(1) (2006) 77-81.
  • [19] S.A. Awad, E.M. Khalaf, Investigation of improvement of thermal and mechanical properties of polypropylene/nano clay composites, International Journal of Chemistry and Technology 2(2) (2018) 129-134.
  • [20] Q. Zhang, S. Rastogi, D. Chen, D. Lippits, P.J. Lemstra, Low percolation threshold in single-walled carbon nanotube/high-density polyethylene composites prepared by melt processing technique, Carbon 44(4) (2006) 778-785.
  • [21] M. Lisunova, Y.P. Mamunya, N. Lebovka, A. Melezhyk, Percolation behaviour of ultrahigh molecular weight polyethylene/multi-walled carbon nanotubes composites, European Polymer Journal 43(3) (2007) 949-958.
  • [22] S.A. Awad, E.M. Khalaf, Evaluation of the photostabilizing efficiency of polyvinyl alcohol–zinc chloride composites, J. Thermoplast. Compos. Mater. (2018) 0892705718804585.
  • [23] A. Diop, F. Mijiyawa, D. Koffi, B.V. Kokta, D. Montplaisir, Study of lignin dispersion in low-density polyethylene, J. Thermoplast. Compos. Mater. 28(12) (2014) 1662-1674.

Year 2018, Volume: 2 Issue: 2, 171 - 179, 29.12.2018

Sameer A. Awad , Eman M. Khalaf

https://doi.org/10.29002/asujse.432715
Cited By: 3

Abstract

References

  • [1] M. Alidadi‐Shamsabadi, T. Behzad, R. Bagheri, B. Nari‐Nasrabadi, Preparation and characterization of low‐density polyethylene/thermoplastic starch composites reinforced by cellulose nanofibers, Polym. Compos. 36(12) (2015) 2309-2316.
  • [2] S.A. Awad, E.M. Khalaf, Evaluation of thermal and mechanical properties of Low-Density Poly Ethylene (LDPE)-Corn Flour (CF) composites. Int. Journal ChemTech Research. 10(13) (2017) 230-235.
  • [3] S.A. Awad, E.M. Khalaf, Improvement of the chemical, thermal, mechanical and morphological properties of polyethylene terephthalate–graphene particle composites, Bull. Mater. Sci. 41(3) (2018) 67.
  • [4] P. Blaszczak, W. Brostow, T. Datashvili, H.E.H. Lobland, Rheology of low‐density polyethylene+ Boehmite composites, Polym. Compos. 31(11) (2010) 1909-1913.
  • [5] S.A. Awad, Influence study of (Vitamin C) absorption on the mechanical properties of (Polyethylene terephthalate) drinking bottles. Journal of University of Anbar for Pure Science 5 (2011) 31-36
  • [6] S. Ghafarizadeh, M. Fréchette, E. David, Fabrication and Dielectric, Mechanical, and Thermal Properties of Low-Density Polyethylene (LDPE) Composites Containing Surface-Passivated Silicon (Si/SiO2 Core/Shell Nanoparticles), Polym. Plast. Technol. Eng. 57(4) (2018) 327-334.
  • [7] E.M. Khalaf, S.A. Awad, Improvement of Mechanical and Water Absorbance Properties of Low-Density Polyethylene (LDPE) by using White Kaolin Powder (WK). J. Adv. Chem. Sci. 3(1) (2017) 426-427.
  • [8] M. Goyal, N. Goyal, H. Kaur, A. Gera, K. Minocha, P. Jindal, Fabrication and characterisation of low density polyethylene (LDPE)/multi walled carbon nanotubes (MWCNTs) nano-composites, Perspectives in Science 8 (2016) 403-405.
  • [9] N. Gray, Y. Hamzeh, A. Kaboorani, A. Abdulkhani, Influence of cellulose nanocrystal on strength and properties of low density polyethylene and thermoplastic starch composites, Industrial Crops and Products 115 (2018) 298-305.
  • [10] E. Khalaf, S. Awad, Improvement of Chemical and Thermal Properties of Polyethylene Terephthalate (PET) by Using Multi-Walled Carbon Nanotubes (MWCNTs), International Journal of Materials Science and Applications 5(6) (2016) 297-301.
  • [11] S.A. Awad, E.M. Khalaf, Improvement chemical, thermal, and mechanical properties of Polypropylene by using corn flour, Usak University Journal of Material Sciences 6(1/2) (2017) 15-25.
  • [12] S. Awad, E. Khalaf, Improvement, the Performance of Polyurethane (PUR), Y-290 Resin as Coating of Oil Pipeline by Using Multi-Walled Carbon Nanotubes (MWCNTs), Engineering and Technology Journal 35(8 Part (A) Engineering) (2017) 845-848.
  • [13] A. Luyt, J. Molefi, H. Krump, Thermal, mechanical and electrical properties of copper powder filled low-density and linear low-density polyethylene composites, Polym.Degrad. .Stab.91(7) (2006) 1629-1636.
  • [14] Y.A. Mubarak, R.T. Abdulsamad, Effects of microcrystalline cellulose on the mechanical properties of low-density polyethylene composites, J. Thermoplast. Compos. Mater. (2018) 0892705717753056.
  • [15] C. Reddy, C. Das, Propylene-ethylene copolymer filled nanocomposites: Influence of Zn-ion coating upon nano-SiO2 on structural, thermal, and dynamic mechanical properties, Polym. Plast.Technol. Eng. 45(7) (2006) 815-820.
  • [16] P. Roy, P. Surekha, C. Rajagopal, S. Chatterjee, V. Choudhary, Accelerated aging of LDPE films containing cobalt complexes as prooxidants, Polym. Degrad. Stab. 91(8) (2006) 1791-1799.
  • [17] K. Şirin, M. Balcan, F. Doğan. The influence of filler component on mechanical properties and thermal analysis of PP-LDPE and PP-LDPE/DAP ternary composites, Polypropylene, InTech, 2012.
  • [18] Z. Wang, M. Lu, H.-L. Li, X.-Y. Guo, SWNTs–polystyrene composites preparations and electrical properties research, Mater. Chem. Phys. 100(1) (2006) 77-81.
  • [19] S.A. Awad, E.M. Khalaf, Investigation of improvement of thermal and mechanical properties of polypropylene/nano clay composites, International Journal of Chemistry and Technology 2(2) (2018) 129-134.
  • [20] Q. Zhang, S. Rastogi, D. Chen, D. Lippits, P.J. Lemstra, Low percolation threshold in single-walled carbon nanotube/high-density polyethylene composites prepared by melt processing technique, Carbon 44(4) (2006) 778-785.
  • [21] M. Lisunova, Y.P. Mamunya, N. Lebovka, A. Melezhyk, Percolation behaviour of ultrahigh molecular weight polyethylene/multi-walled carbon nanotubes composites, European Polymer Journal 43(3) (2007) 949-958.
  • [22] S.A. Awad, E.M. Khalaf, Evaluation of the photostabilizing efficiency of polyvinyl alcohol–zinc chloride composites, J. Thermoplast. Compos. Mater. (2018) 0892705718804585.
  • [23] A. Diop, F. Mijiyawa, D. Koffi, B.V. Kokta, D. Montplaisir, Study of lignin dispersion in low-density polyethylene, J. Thermoplast. Compos. Mater. 28(12) (2014) 1662-1674.
There are 23 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Article
Authors

Sameer A. Awad 0000-0002-9194-719X

Eman M. Khalaf

Publication Date December 29, 2018
Submission Date June 12, 2018
Acceptance Date December 19, 2018
Published in Issue Year 2018Volume: 2 Issue: 2

Cite

APA Awad, S. A., & Khalaf, E. M. (2018). Characterisation and Performance of Low-Density Poly Ethylene-Corn Flour Composites. Aksaray University Journal of Science and Engineering, 2(2), 171-179. https://doi.org/10.29002/asujse.432715

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Enhancing the Thermal and Mechanical Characteristics of Polyvinyl Alcohol (PVA)-Hemp Protein Particles (HPP) Composites
International Polymer Processing
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https://doi.org/10.1515/ipp-2020-3974
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