Year 2019, Volume 3 , Issue 1, Pages 29 - 42 2019-06-30

Effects of Synthesis Conditions on the PdCu Membrane Structure

Saliha Cetinyokus [1] , Meltem Dogan [2] , Nesli Kucuktepe [3]


In this study, it was aimed to plate PdCu alloy layer on porous glass supports by using electroless plating technique. It was also aimed to achieve coexistence of fcc (face-centered cubic) and bcc (body-centered cubic) phases on the alloy membrane layer. The fcc and bcc phases were seen together in the structures of the membranes synthesized at all three bath temperatures (30 °C, 40 °C and 50 °C), but, it was shown that the most suitable coating rate was achieved when the coating bath temperature was 40 °C. The appropriate composition of PdCu (74% Pd, 26% Cu) was achieved by following a synthesis procedure as follows: Coating in Pd bath three times for 60 minutes each followed by coating in Cu bath at the low formaldehyde concentration (5 mL/L) for 15 minutes. Hydrogen flux in the membrane was measured as 1.9x10-6 mol/cm2s. After flux measurements, it was determined that the membrane structure changed and the fcc (200) structure, which did not previously exist in the structure, was formed.

Electroless plating, PdCu, Composite membrane, Characterization
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Primary Language en
Subjects Engineering
Published Date June 2019
Journal Section Research Article
Authors

Orcid: 0000-0001-9955-6428
Author: Saliha Cetinyokus (Primary Author)
Institution: GAZİ VOCATIONAL SCHOOL
Country: Turkey


Author: Meltem Dogan
Institution: Gazı University
Country: Turkey


Author: Nesli Kucuktepe
Institution: Turkey Directorate General of Coal Enterprises, R&D Department Presidency
Country: Turkey


Dates

Publication Date : June 30, 2019

Bibtex @research article { asujse527882, journal = {Aksaray University Journal of Science and Engineering}, issn = {}, eissn = {2587-1277}, address = {Aksaray Üniversitesi, Fen Bilimleri Enstitüsü, Merkez Kampüs, 68100 Aksaray}, publisher = {Aksaray University}, year = {2019}, volume = {3}, pages = {29 - 42}, doi = {10.29002/asujse.527882}, title = {Effects of Synthesis Conditions on the PdCu Membrane Structure}, key = {cite}, author = {Cetinyokus, Saliha and Dogan, Meltem and Kucuktepe, Nesli} }
APA Cetinyokus, S , Dogan, M , Kucuktepe, N . (2019). Effects of Synthesis Conditions on the PdCu Membrane Structure. Aksaray University Journal of Science and Engineering , 3 (1) , 29-42 . DOI: 10.29002/asujse.527882
MLA Cetinyokus, S , Dogan, M , Kucuktepe, N . "Effects of Synthesis Conditions on the PdCu Membrane Structure". Aksaray University Journal of Science and Engineering 3 (2019 ): 29-42 <http://asujse.aksaray.edu.tr/en/issue/41539/527882>
Chicago Cetinyokus, S , Dogan, M , Kucuktepe, N . "Effects of Synthesis Conditions on the PdCu Membrane Structure". Aksaray University Journal of Science and Engineering 3 (2019 ): 29-42
RIS TY - JOUR T1 - Effects of Synthesis Conditions on the PdCu Membrane Structure AU - Saliha Cetinyokus , Meltem Dogan , Nesli Kucuktepe Y1 - 2019 PY - 2019 N1 - doi: 10.29002/asujse.527882 DO - 10.29002/asujse.527882 T2 - Aksaray University Journal of Science and Engineering JF - Journal JO - JOR SP - 29 EP - 42 VL - 3 IS - 1 SN - -2587-1277 M3 - doi: 10.29002/asujse.527882 UR - https://doi.org/10.29002/asujse.527882 Y2 - 2019 ER -
EndNote %0 Aksaray University Journal of Science and Engineering Effects of Synthesis Conditions on the PdCu Membrane Structure %A Saliha Cetinyokus , Meltem Dogan , Nesli Kucuktepe %T Effects of Synthesis Conditions on the PdCu Membrane Structure %D 2019 %J Aksaray University Journal of Science and Engineering %P -2587-1277 %V 3 %N 1 %R doi: 10.29002/asujse.527882 %U 10.29002/asujse.527882
ISNAD Cetinyokus, Saliha , Dogan, Meltem , Kucuktepe, Nesli . "Effects of Synthesis Conditions on the PdCu Membrane Structure". Aksaray University Journal of Science and Engineering 3 / 1 (June 2019): 29-42 . https://doi.org/10.29002/asujse.527882
AMA Cetinyokus S , Dogan M , Kucuktepe N . Effects of Synthesis Conditions on the PdCu Membrane Structure. Aksaray J. Sci. Eng.. 2019; 3(1): 29-42.
Vancouver Cetinyokus S , Dogan M , Kucuktepe N . Effects of Synthesis Conditions on the PdCu Membrane Structure. Aksaray University Journal of Science and Engineering. 2019; 3(1): 42-29.