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Optimization of Electro-Oxidation Process Assisted by S2O82-, H2O2 and O3 Using Graphite Cathode and Multiple Metal Oxide Coated Ti Anodes

Year 2024, EARLY VIEW, 1 - 1

Nevim Genç Elif Durna Pişkin

https://doi.org/10.2339/politeknik.1284751

Abstract

The treatment of real textile wastewater was carried out in the oxidant assisted electro-oxidation (EO) process, in which coated and uncoated titanium with multiple metal oxides as the anode and graphite rod as the cathode were used. The performance of EO process assisted with S2O82-, H2O2 and O3 as oxidant was evaluated with Pt-Co, number of colors and COD removal efficiencies. Process conditions were optimized with Taguchi Experimental Design. Parameters with significant effects on performance variables were determined with ANOVA. Optimum conditions of the oxidant assisted EO process were determined as RuO2-IrO2-Ti anode, oxidant type S2O82-, pH 3.0, 25 minutes oxidation time. Pt-Co, color number and COD removal efficiencies at optimum conditions were obtained as 83.37%, 82.6 % and 51.17%, respectively. From the ANOVA results, it was determined that the most important operating parameter among all response parameters was the oxidation time.

Keywords

Electro-oxidation oxidant multiple metal oxide coated Ti graphite optimization

References

  • [1] Deng Y., Zhu X., Chen N., Feng C., Wang H., Kuang P. and Hu W. “Review on electrochemical system for landfill leachate treatment: Performance, mechanism, application, shortcoming, and improvement scheme”, The Science of the Total Environment, 745: (2020).
  • [2] Panizza M. and Cerisola G., “Direct and mediated anodic oxidation of organic pollutants”, Chemical Reviews, 109: 6541–69, (2009).
  • [3] Ganiyu SO., Martínez-Huitle CA. and Oturan MA., “Electrochemical advanced oxidation processes for wastewater treatment: Advances in formation and detection of reactive species and mechanisms”, Current Opinion in Electrochemistry, 27: 100678, (2021).
  • [4] Karaoğlu AG., Öztürk D., Akyol A. and Kara S., “PCT degradation with electrooxidation (EOx) and ultrasound (US) hybrid process using different type electrodes: BDD, Ti/PbO2 and Ti/Pt”, Separation and Purification Technology, 311: 123313, (2023).
  • [5] Köktaş İY., Gökkuş Ö., Kariper İA. and Othmani A. “Tetracycline removal from aqueous solution by electrooxidation using ruthenium-coated graphite anode”, Chemosphere, 315: 137758, (2023).
  • [6] Spuhler D., Andrés Rengifo-Herrera J. and Pulgarin C., “The effect of Fe2+, Fe3+, H2O2 and the photo-Fenton reagent at near neutral pH on the solar disinfection (SODIS) at low temperatures of water containing Escherichia coli K12”, Applied Catalysis B: Environmental, 96: 126–41, (2010).
  • [7] Iqbal A., Yusaf A., Usman M., Hussain Bokhari T. and Mansha A., “Insight into the degradation of different classes of dyes by advanced oxidation processes; a detailed review”, International Journal of Environmental Analytical Chemistry, 1-35, (2023).
  • [8] Tao NC. and Luu T Le., “Different behaviours of biologically textile wastewater treatment using persulfate catalyzed electrochemical oxidation process on Ti/BDD and Ti/SnO2-Nb2O5 anodes”, Environmental Engineering Research, 28: 220555, (2023).
  • [9] Yao J., Zhang Y. and Dong Z., “Enhanced degradation of contaminants of emerging concern by electrochemically activated peroxymonosulfate: Performance, mechanism, and influencing factors”, Chemical Engineering Journal, 415: 128938, (2021).
  • [10] Gao Q., Ding J., Zhao G., Zhao Q., Li L., Zhao X., Bu L., Zhou S. and Qiu S., “Exploring the synergism of sunlight and electrooxidation on persulfate activation for efficient degradation of bisphenol S: Performance, Pathway, and mechanism”, Chemical Engineering Journal, 437: 135318, (2022).
  • [11] Wang F, Wu C, Li Q., “Treatment of refractory organics in strongly alkaline dinitrodiazophenol wastewater with microwave irradiation-activated persulfate”. Chemosphere, 254: 126773, (2020).
  • [12] Genç N, Durna Pişkin E, Kacıra E., “Optimization of Synergistic Radical-Based Processes for the Treatment of Membrane Leachate Concentrate: Selection of the Most Suitable Process by PROMETHEE Approach”, Water, Air, and Soil Pollution, 234: 1–14, (2023).
  • [13] Himmetoğlu S, Kızılkaya Aydogan E, Özcan F, Karahan O, Atiş C., “Rough-AHP and MOORA-based Taguchi Optimization for Mixture Proportion of Building Concrete”, Journal of Polytechnic, 1-1, (2022).
  • [14] Sadrzadeh M. and Mohammadi T., “Sea water desalination using electrodialysis”, Desalination, 221: 440–7, (2008).
  • [15] Erdemir F. and Ozkan MT., “Application of Taguchi Method for Optimization of Design Parameters in Enhancement The Robust of ‘C’ Type Snap-fits”, Journal of Polytechnic, 25: 1385–95, (2022).
  • [16] Akgün M and Demir H., “Optimization and finite element modelling of tool wear in milling of inconel 625 superalloy”, Politeknik Dergisi, 24, 391–400, (2021).
  • [17] Aber S., Salari D. and Parsa MR., “Employing the Taguchi method to obtain the optimum conditions of coagulation–flocculation process in tannery wastewater treatment”, Chemical Engineering Journal, 162: 127–34, (2010).
  • [18] Dhawane SH., Kumar T. and Halder G., “Biodiesel synthesis from Hevea brasiliensis oil employing carbon supported heterogeneous catalyst: Optimization by Taguchi method”, Renewable Energy, 89: 506–14, (2016).
  • [19] Gupta GK., Mondal MK.. “Bio-energy generation from sagwan sawdust via pyrolysis: Product distributions, characterizations and optimization using response surface methodology”, Energy, 170: 423–37, (2019).
  • [20] Silveira JE., Garcia-Costa AL., Cardoso TO., Zazo JA. and Casas JA., “Indirect decolorization of azo dye Disperse Blue 3 by electro-activated persulfate”, Electrochimica Acta, 258: 927–32, (2017).

Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu

Year 2024, EARLY VIEW, 1 - 1

Nevim Genç Elif Durna Pişkin

https://doi.org/10.2339/politeknik.1284751

Abstract

Anot olarak karışık metal oksitler ile kaplanmış ve kaplanmamış titanyum ve katot olarak ise grafit çubuğunun kullanıldığı, oksidant ile desteklenmiş elektro-oksidasyon (EO) prosesinde gerçek tekstil atık suyunun arıtımı gerçekleştirilmiştir. Oksidant olarak S2O82-, H2O2 ve O3 ile desteklenmiş proseslerin performansı, Pt-Co giderim verimi, renk sayısı giderim verimi ve KOİ giderim verimleri ile değerlendirilmiştir. Proses koşulları Taguchi Deney Tasarımı ile optimize edilmiştir. ANOVA ile performans değişkenleri üzerine önemli etkiye sahip parametreler belirlenmiştir. Oksidant destekli EO prosesinin optimum koşulları; RuO2-IrO2-Ti anot, oksidant tipi S2O82-, pH 3,0, oksidasyon süresi 25 dakika olarak belirlenmiştir. Bu koşullarda, Pt-Co, renk sayısı ve KOİ giderim verimleri (%) sırası ile 83,37, 82,6 ve 51,17 olarak elde edilmiştir. ANOVA sonuçlarından tüm yanıt parametreleri için en önemli işletim parametresinin oksidasyon süresi olduğu ortaya çıkmıştır.

Keywords

Elektro-oksidasyon oksidant karışık metal oksit kaplı Ti grafit optimizasyon

References

  • [1] Deng Y., Zhu X., Chen N., Feng C., Wang H., Kuang P. and Hu W. “Review on electrochemical system for landfill leachate treatment: Performance, mechanism, application, shortcoming, and improvement scheme”, The Science of the Total Environment, 745: (2020).
  • [2] Panizza M. and Cerisola G., “Direct and mediated anodic oxidation of organic pollutants”, Chemical Reviews, 109: 6541–69, (2009).
  • [3] Ganiyu SO., Martínez-Huitle CA. and Oturan MA., “Electrochemical advanced oxidation processes for wastewater treatment: Advances in formation and detection of reactive species and mechanisms”, Current Opinion in Electrochemistry, 27: 100678, (2021).
  • [4] Karaoğlu AG., Öztürk D., Akyol A. and Kara S., “PCT degradation with electrooxidation (EOx) and ultrasound (US) hybrid process using different type electrodes: BDD, Ti/PbO2 and Ti/Pt”, Separation and Purification Technology, 311: 123313, (2023).
  • [5] Köktaş İY., Gökkuş Ö., Kariper İA. and Othmani A. “Tetracycline removal from aqueous solution by electrooxidation using ruthenium-coated graphite anode”, Chemosphere, 315: 137758, (2023).
  • [6] Spuhler D., Andrés Rengifo-Herrera J. and Pulgarin C., “The effect of Fe2+, Fe3+, H2O2 and the photo-Fenton reagent at near neutral pH on the solar disinfection (SODIS) at low temperatures of water containing Escherichia coli K12”, Applied Catalysis B: Environmental, 96: 126–41, (2010).
  • [7] Iqbal A., Yusaf A., Usman M., Hussain Bokhari T. and Mansha A., “Insight into the degradation of different classes of dyes by advanced oxidation processes; a detailed review”, International Journal of Environmental Analytical Chemistry, 1-35, (2023).
  • [8] Tao NC. and Luu T Le., “Different behaviours of biologically textile wastewater treatment using persulfate catalyzed electrochemical oxidation process on Ti/BDD and Ti/SnO2-Nb2O5 anodes”, Environmental Engineering Research, 28: 220555, (2023).
  • [9] Yao J., Zhang Y. and Dong Z., “Enhanced degradation of contaminants of emerging concern by electrochemically activated peroxymonosulfate: Performance, mechanism, and influencing factors”, Chemical Engineering Journal, 415: 128938, (2021).
  • [10] Gao Q., Ding J., Zhao G., Zhao Q., Li L., Zhao X., Bu L., Zhou S. and Qiu S., “Exploring the synergism of sunlight and electrooxidation on persulfate activation for efficient degradation of bisphenol S: Performance, Pathway, and mechanism”, Chemical Engineering Journal, 437: 135318, (2022).
  • [11] Wang F, Wu C, Li Q., “Treatment of refractory organics in strongly alkaline dinitrodiazophenol wastewater with microwave irradiation-activated persulfate”. Chemosphere, 254: 126773, (2020).
  • [12] Genç N, Durna Pişkin E, Kacıra E., “Optimization of Synergistic Radical-Based Processes for the Treatment of Membrane Leachate Concentrate: Selection of the Most Suitable Process by PROMETHEE Approach”, Water, Air, and Soil Pollution, 234: 1–14, (2023).
  • [13] Himmetoğlu S, Kızılkaya Aydogan E, Özcan F, Karahan O, Atiş C., “Rough-AHP and MOORA-based Taguchi Optimization for Mixture Proportion of Building Concrete”, Journal of Polytechnic, 1-1, (2022).
  • [14] Sadrzadeh M. and Mohammadi T., “Sea water desalination using electrodialysis”, Desalination, 221: 440–7, (2008).
  • [15] Erdemir F. and Ozkan MT., “Application of Taguchi Method for Optimization of Design Parameters in Enhancement The Robust of ‘C’ Type Snap-fits”, Journal of Polytechnic, 25: 1385–95, (2022).
  • [16] Akgün M and Demir H., “Optimization and finite element modelling of tool wear in milling of inconel 625 superalloy”, Politeknik Dergisi, 24, 391–400, (2021).
  • [17] Aber S., Salari D. and Parsa MR., “Employing the Taguchi method to obtain the optimum conditions of coagulation–flocculation process in tannery wastewater treatment”, Chemical Engineering Journal, 162: 127–34, (2010).
  • [18] Dhawane SH., Kumar T. and Halder G., “Biodiesel synthesis from Hevea brasiliensis oil employing carbon supported heterogeneous catalyst: Optimization by Taguchi method”, Renewable Energy, 89: 506–14, (2016).
  • [19] Gupta GK., Mondal MK.. “Bio-energy generation from sagwan sawdust via pyrolysis: Product distributions, characterizations and optimization using response surface methodology”, Energy, 170: 423–37, (2019).
  • [20] Silveira JE., Garcia-Costa AL., Cardoso TO., Zazo JA. and Casas JA., “Indirect decolorization of azo dye Disperse Blue 3 by electro-activated persulfate”, Electrochimica Acta, 258: 927–32, (2017).
There are 20 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Article
Authors

Nevim Genç 0000-0002-6185-1090

Elif Durna Pişkin 0000-0003-4478-2967

Early Pub Date September 4, 2023
Publication Date
Submission Date April 17, 2023
Published in Issue Year 2024 EARLY VIEW

Cite

APA Genç, N., & Durna Pişkin, E. (2023). Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu. Politeknik Dergisi1-1. https://doi.org/10.2339/politeknik.1284751
AMA Genç N, Durna Pişkin E. Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu. Politeknik Dergisi. Published online September 1, 2023:1-1. doi:10.2339/politeknik.1284751
Chicago Genç, Nevim, and Elif Durna Pişkin. “Grafit Katot Ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 Ve O3 Ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu”. Politeknik Dergisi, September (September 2023), 1-1. https://doi.org/10.2339/politeknik.1284751.
EndNote Genç N, Durna Pişkin E (September 1, 2023) Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu. Politeknik Dergisi 1–1.
IEEE N. Genç and E. Durna Pişkin, “Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu”, Politeknik Dergisi, pp. 1–1, September 2023, doi: 10.2339/politeknik.1284751.
ISNAD Genç, Nevim - Durna Pişkin, Elif. “Grafit Katot Ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 Ve O3 Ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu”. Politeknik Dergisi. September 2023. 1-1. https://doi.org/10.2339/politeknik.1284751.
JAMA Genç N, Durna Pişkin E. Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu. Politeknik Dergisi. 2023;:1–1.
MLA Genç, Nevim and Elif Durna Pişkin. “Grafit Katot Ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 Ve O3 Ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu”. Politeknik Dergisi, 2023, pp. 1-1, doi:10.2339/politeknik.1284751.
Vancouver Genç N, Durna Pişkin E. Grafit Katot ve Karışık Metal Oksit Kaplı Ti Anotların Kullanıldığı S2O82-, H2O2 ve O3 ile Desteklenen Elektro-Oksidasyon Prosesinin Optimizasyonu. Politeknik Dergisi. 2023:1-.

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