Research Article
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Year 2023, Issue: 053, 59 - 73, 30.06.2023
https://doi.org/10.59313/jsr-a.1243469

Abstract

References

  • [1] Turan, M.D., Altundoǧan, H.S., and Tümen, F. (2004). Recovery of zinc and lead from zinc plant residue. Hydrometallurgy, 75, 169–176. https://doi.org/10.1016/j.hydromet.2004.07.008
  • [2] Kursunoglu, S., Top, S., and Kaya, M. (2020). Recovery of zinc and lead from Yahyali non-sulphide flotation tailing by sequential acidic and sodium hydroxide leaching in the presence of potassium sodium tartrate. Transactions of Nonferrous Metals Society of China, 30, 3367–3378. https://doi.org/10.1016/S1003-6326(20)65468-1
  • [3] Hussaini, S., Kursunoglu, S., Top, S., Ichlas, Z.T., and Kaya, M. (2021). Testing of 17-different leaching agents for the recovery of zinc from a carbonate-type Pb-Zn ore flotation tailing. Miner. Eng., 168, 106935, 1–29. https://doi.org/10.1016/j.mineng.2021.106935
  • [4] Şentürk, B., Özbayoğlu, G., and Atalay, Ü. (1993). Flotation of lead-zinc carbonate ore of Kayseri̇-Zamanti district (in Turkish). Türkiye XIII Madencilik Kongresi, 459–466.
  • [5] Önal, G., Bulut, G., Gül, A., Kangal, O., Perek, K.T., and Arslan, F. (2005). Flotation of Aladaǧ oxide lead-zinc ores. Minerals Engineering, 18, 279–282. https://doi.org/10.1016/j.mineng.2004.10.018
  • [6] Hosseini, S.H. and Taji, M. (2015). Flotation behavior of Iranian oxidized zinc ore using different types of collectors (cationic, anionic and mixed (cationic/anionic)). International Journal of Mining Engineering and Mineral Processing, 4, 18–27. https://doi.org/10.5923/j.mining.20150401.03
  • [7] Rashchi, F., Dashti, A., Arabpour-Yazdi, M., and Abdizadeh, H. (2005). Anglesite flotation: a study for lead recovery from zinc leach residue. Minerals Engineering, 18, 205–212. https://doi.org/10.1016/j.mineng.2004.10.014
  • [8] Pirajno, F., Burlow, R., and Huston, D. (2010). The Magellan Pb deposit, Western Australia; a new category within the class of supergene non-sulphide mineral systems. Ore Geology Reviews, 37, 101–113. https://doi.org/10.1016/j.oregeorev.2010.01.001
  • [9] Koski, R.A. (2010). Supergene ore and gangue characteristics. USGS, 181-189.
  • [10] Yoğurtcuoğlu, E. (2022). Metal recovery from oxidized ore tailings with organic acid (in Turkish). 2nd International Conference on Environment, Technology and Management (ICETEM), 263–271.
  • [11] Demir, F., Laçin, O. and Dönmez, B. (2006). Leaching kinetics of calcined magnesite in citric acid solutions. Ind. Eng. Chem. Res., 45, 1307–1311. https://doi.org/10.1016/j.jiec.2009.09.014
  • [12] Larba, R., Boukerche, I., Alane, N., Habbache, N., Djerad, S., and Tifouti, L. (2013). Citric acid as an alternative lixiviant for zinc oxide dissolution. Hydrometallurgy, 134–135, 117–123. https://doi.org/10.1016/j.hydromet.2013.02.002
  • [13] Halli, P., Hamuyuni, J., Leikola, M. and Lundström, M. (2018). Developing a sustainable solution for recycling electric arc furnace dust via organic acid leaching. Minerals Engineering, 124, 1–9. https://doi.org/10.1016/j.mineng.2018.05.011
  • [14] Kaya, M., Hussaini, S., and Kursunoglu, S. (2020). Critical review on secondary zinc resources and their recycling technologies. Hydrometallurgy, 195, 105362. https://doi.org/10.1016/j.hydromet.2020.105362
  • [15] Cengiç, S. (2007). Recovery of zinc wastes by hydrometallurgical methods (in Turkish). Yildiz Teknik Üniversitesi.
  • [16] Xia, Z., Zhang, X., Huang, X., Yang, S., Chen, Y., and Ye, L. (2020). Hydrometallurgical stepwise recovery of copper and zinc from smelting slag of waste brass in ammonium chloride solution. Hydrometallurgy, 197, 105475. https://doi.org/10.1016/j.hydromet.2020.105475
  • [17] Zhang, J., Hendrix, J.L., Kappes, D.W., and Albert, T.E. (1993). Recovery of gold and silver from a sulfidic ore cyanide and chloride leaching after chlorination roasting. Society for Mining, Metallurgy & Exploration, 311–326.
  • [18] Liao, M.X. and Deng, T.L. (2004). Zinc and lead extraction from complex raw sulfides by sequential bioleaching and acidic brine leach. Minerals Engineering, 17, 17–22. https://doi.org/10.1016/J.MINENG.2003.09.007
  • [19] Ruşen, A., Sunkar, A.S., and Topkaya, Y.A. (2008). Zinc and lead extraction from Çinkur leach residues by using hydrometallurgical method. Hydrometallurgy, 93, 45–50. https://doi.org/10.1016/J.HYDROMET.2008.02.018
  • [20] Farahmand, F., Moradkhani, D., Safarzadeh, M.S., and Rashchi, F. (2009). Brine leaching of lead-bearing zinc plant residues: process optimization using orthogonal array design methodology. Hydrometallurgy, 95, 316–324. https://doi.org/10.1016/j.hydromet.2008.07.012
  • [21] Silwamba, M., Ito, M., Hiroyoshi, N., Tabelin, C.B., Fukushima, T., Park, I., Jeon, S., Igarashi, T., Sato, T., Nyambe, I., Chirwa, M., Banda, K., Nakata, H., Nakayama, S., and Ishizuka, M. (2020). Detoxification of lead-bearing zinc plant leach residues from Kabwe, Zambia by coupled extraction-cementation method. Journal of Environmental Chemical Engineering, 8, 104197. https://doi.org/10.1016/j.jece.2020.104197
  • [22] Gammons, C.H. and Williams-Tones, A.E. (1995). The solubility of Au-Ag alloy + AgCl in HCl/NaCl solutions at 300°C: new data on the stability of Au (1) chloride complexes in hydrothermal fluids. Geochimica et Cosmochimica Acta, 59, 3453–3468. https://doi.org/10.1016/0016-7037(95)00234-Q
  • [23] Tagirov, B.R., Zotov, A. V., and Akinfiev, N.N. (1997). Experimental study of dissociation of HCl from 350 to 500°C and from 500 to 2500 bars: thermodynamic properties of HCl°(aq). Geochimica et Cosmochimica Acta, 61, 4267–4280. https://doi.org/10.1016/S0016-7037(97)00274-3
  • [24] Bahram, B. and Javad, M. (2011). Chloride leaching of lead and silver from refractory zinc plant residue. Research Journal of Chemistry and Environment, 15, 1–8.
  • [25] Raghavan, R., Mohanan, P.K., and Patnaik, S.C. (1998). Innovative processing technique to produce zinc concentrate from zinc leach residue with simultaneous recovery of lead and silver. Hydrometallurgy, 48, 225–237. https://doi.org/10.1016/S0304-386X(97)00082-0
  • [26] Raghavan, R., Mohanan, P.K., and Swarnkar, S.R. (2000). Hydrometallurgical processing of lead-bearing materials for the recovery of lead and silver as lead concentrate and lead metal. Hydrometallurgy, 58, 103–116. http,s://doi.org/10.1016/S0304-386X(00)00108-0
  • [27] Zárate-gutiérrez, R., Lapidus, G.T., and Morales, R.D. (2010). Hydrometallurgy pressure leaching of a lead–zinc–silver concentrate with nitric acid at moderate temperatures between 130 and 170 °C. Hydrometallurgy, 104, 8–13. https://doi.org/10.1016/j.hydromet.2010.04.001
  • [28] Basir, S.M.A. and Rabah, M.A. (1999). Hydrometallurgical recovery of metal values from brass melting slag. Hydrometallurgy, 53, 31–44.
  • [29] Liu, Q., Zhao, Y., and Zhao, G. (2011). Production of zinc and lead concentrates from lean oxidized zinc ores by alkaline leaching followed by two-step precipitation using sulfides. Hydrometallurgy, 110, 79–84. https://doi.org/10.1016/J.HYDROMET.2011.08.009
  • [30] Jiang, G., Peng, B., Liang, Y., Chai, L., Wang, Q., Li, Q., and Hu, M. (2017). Recovery of valuable metals from zinc leaching residue by sulfate roasting and water leaching. Transactions of Nonferrous Metals Society of China (English edition), 27, 1180–1187. https://doi.org/10.1016/S1003-6326(17)60138-9
  • [31] Yoğurtcuoğlu, E. (2022). Evaluation of flotation wastes of oxidised ores (in Turkish). IV International Turkic World Congress on Science and Engineering (TURK-COSE), 1098–1104.
  • [32] Ju, S., Motang, T., Shenghai, Y., and Yingnian, L. (2005). Dissolution kinetics of smithsonite ore in ammonium chloride solution. Hydrometallurgy, 80, 67–74. https://doi.org/10.1016/j.hydromet.2005.07.003
  • [33] Chen, A., Zhao, Z. W., Jia, X., Long, S., Huo, G., and Chen, X. (2009). Alkaline leaching Zn and its concomitant metals from refractory hemimorphite zinc oxide ore. Hydrometallurgy, 97, 228–232. https://doi.org/10.1016/j.hydromet.2009.01.005
  • [34] Dou, A.C., Yang, T.Z., Yang, J.X., Wu, J.H., and Wang, A. (2011). Leaching of low grade zinc oxide ores in Ida2-- H2O system. Transactions of Nonferrous Metals Society of China (English edition), 21, 2548–2553. https://doi.org/10.1016/S1003-6326(11)61049-2
  • [35] Irannajad, M., Meshkini, M., and Azadmehr, A.R. (2013). Leaching of zinc from low grade oxide ore using organic acid. Physicochemical Problems of Mineral Processing, 49, 547–555. https://doi.org/10.5277/ppmp130215
  • [36] Güler, E., Seyrankaya, A., and Cöcen, I. (2011). Hydrometallurgical evaluation of zinc leach plant residue. Asian Journal of Chemistry, 23, 2879–2888.
  • [37] Yoğurtcuoğlu, E. (2022). Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir University Journal of Engineering Sciences, 11, 819–825. https://doi.org/10.28948/ngmuh.
  • [38] Yoğurtcuoğlu, E. (2022). The citric acid leaching of boron process wastes (early access). Canadian Metallurgical Quarterly, 1–18. https://doi.org/10.1080/00084433.2022.2131132

MULTI-METAL RECOVERY FROM FLOTATION TAILINGS WITH CITRIC ACID ON THE NACl MEDIA

Year 2023, Issue: 053, 59 - 73, 30.06.2023
https://doi.org/10.59313/jsr-a.1243469

Abstract

After the flotation process of oxidized lead-zinc ores, the high amount of metal (especially zinc metal) in its content cannot be recovered and is stored as waste. Ore and (therefore) tailings are found together with gangue minerals such as calcite, and dolomite, which are oxide/carbonate minerals. Precious minerals are zinc, lead, silver, and iron-containing minerals such as smithsonite, hydrozincite, plumbojarosite, and goethite. The particle size of the sample taken from this waste was determined as d80= 78.22µm. In order to recover these ore wastes with high metal content, the dissolution of citric acid, which is a weak organic acid, in NaCl medium was investigated. When the study was examined at a concentration of 0.5 M citric acid and 200 g/L NaCl, for 1 hour at 60 ℃, 10% solids, it was found that 66.85% Zn, 56.53% Pb, 40.68% Ag, and 27.74% Fe were dissolved. According to the results of this experiment, keeping each of these parameters constant, 0.125-1 M citric acid, 50-400 g/L NaCl, 15-120 minutes leaching time, 25-95 ℃ leaching temperature, and 5-40% solids metal. The efficiency of the gain yields was tried to be determined. When the final results are examined, there are 60-80% zinc, 40-70% lead, 0.01-35% iron, and 11-83% silver recovery efficiencies. In light of these results, it is thought that industrial-scale improvements in multi-metal recovery from oxidized ore wastes may improve positive results.

References

  • [1] Turan, M.D., Altundoǧan, H.S., and Tümen, F. (2004). Recovery of zinc and lead from zinc plant residue. Hydrometallurgy, 75, 169–176. https://doi.org/10.1016/j.hydromet.2004.07.008
  • [2] Kursunoglu, S., Top, S., and Kaya, M. (2020). Recovery of zinc and lead from Yahyali non-sulphide flotation tailing by sequential acidic and sodium hydroxide leaching in the presence of potassium sodium tartrate. Transactions of Nonferrous Metals Society of China, 30, 3367–3378. https://doi.org/10.1016/S1003-6326(20)65468-1
  • [3] Hussaini, S., Kursunoglu, S., Top, S., Ichlas, Z.T., and Kaya, M. (2021). Testing of 17-different leaching agents for the recovery of zinc from a carbonate-type Pb-Zn ore flotation tailing. Miner. Eng., 168, 106935, 1–29. https://doi.org/10.1016/j.mineng.2021.106935
  • [4] Şentürk, B., Özbayoğlu, G., and Atalay, Ü. (1993). Flotation of lead-zinc carbonate ore of Kayseri̇-Zamanti district (in Turkish). Türkiye XIII Madencilik Kongresi, 459–466.
  • [5] Önal, G., Bulut, G., Gül, A., Kangal, O., Perek, K.T., and Arslan, F. (2005). Flotation of Aladaǧ oxide lead-zinc ores. Minerals Engineering, 18, 279–282. https://doi.org/10.1016/j.mineng.2004.10.018
  • [6] Hosseini, S.H. and Taji, M. (2015). Flotation behavior of Iranian oxidized zinc ore using different types of collectors (cationic, anionic and mixed (cationic/anionic)). International Journal of Mining Engineering and Mineral Processing, 4, 18–27. https://doi.org/10.5923/j.mining.20150401.03
  • [7] Rashchi, F., Dashti, A., Arabpour-Yazdi, M., and Abdizadeh, H. (2005). Anglesite flotation: a study for lead recovery from zinc leach residue. Minerals Engineering, 18, 205–212. https://doi.org/10.1016/j.mineng.2004.10.014
  • [8] Pirajno, F., Burlow, R., and Huston, D. (2010). The Magellan Pb deposit, Western Australia; a new category within the class of supergene non-sulphide mineral systems. Ore Geology Reviews, 37, 101–113. https://doi.org/10.1016/j.oregeorev.2010.01.001
  • [9] Koski, R.A. (2010). Supergene ore and gangue characteristics. USGS, 181-189.
  • [10] Yoğurtcuoğlu, E. (2022). Metal recovery from oxidized ore tailings with organic acid (in Turkish). 2nd International Conference on Environment, Technology and Management (ICETEM), 263–271.
  • [11] Demir, F., Laçin, O. and Dönmez, B. (2006). Leaching kinetics of calcined magnesite in citric acid solutions. Ind. Eng. Chem. Res., 45, 1307–1311. https://doi.org/10.1016/j.jiec.2009.09.014
  • [12] Larba, R., Boukerche, I., Alane, N., Habbache, N., Djerad, S., and Tifouti, L. (2013). Citric acid as an alternative lixiviant for zinc oxide dissolution. Hydrometallurgy, 134–135, 117–123. https://doi.org/10.1016/j.hydromet.2013.02.002
  • [13] Halli, P., Hamuyuni, J., Leikola, M. and Lundström, M. (2018). Developing a sustainable solution for recycling electric arc furnace dust via organic acid leaching. Minerals Engineering, 124, 1–9. https://doi.org/10.1016/j.mineng.2018.05.011
  • [14] Kaya, M., Hussaini, S., and Kursunoglu, S. (2020). Critical review on secondary zinc resources and their recycling technologies. Hydrometallurgy, 195, 105362. https://doi.org/10.1016/j.hydromet.2020.105362
  • [15] Cengiç, S. (2007). Recovery of zinc wastes by hydrometallurgical methods (in Turkish). Yildiz Teknik Üniversitesi.
  • [16] Xia, Z., Zhang, X., Huang, X., Yang, S., Chen, Y., and Ye, L. (2020). Hydrometallurgical stepwise recovery of copper and zinc from smelting slag of waste brass in ammonium chloride solution. Hydrometallurgy, 197, 105475. https://doi.org/10.1016/j.hydromet.2020.105475
  • [17] Zhang, J., Hendrix, J.L., Kappes, D.W., and Albert, T.E. (1993). Recovery of gold and silver from a sulfidic ore cyanide and chloride leaching after chlorination roasting. Society for Mining, Metallurgy & Exploration, 311–326.
  • [18] Liao, M.X. and Deng, T.L. (2004). Zinc and lead extraction from complex raw sulfides by sequential bioleaching and acidic brine leach. Minerals Engineering, 17, 17–22. https://doi.org/10.1016/J.MINENG.2003.09.007
  • [19] Ruşen, A., Sunkar, A.S., and Topkaya, Y.A. (2008). Zinc and lead extraction from Çinkur leach residues by using hydrometallurgical method. Hydrometallurgy, 93, 45–50. https://doi.org/10.1016/J.HYDROMET.2008.02.018
  • [20] Farahmand, F., Moradkhani, D., Safarzadeh, M.S., and Rashchi, F. (2009). Brine leaching of lead-bearing zinc plant residues: process optimization using orthogonal array design methodology. Hydrometallurgy, 95, 316–324. https://doi.org/10.1016/j.hydromet.2008.07.012
  • [21] Silwamba, M., Ito, M., Hiroyoshi, N., Tabelin, C.B., Fukushima, T., Park, I., Jeon, S., Igarashi, T., Sato, T., Nyambe, I., Chirwa, M., Banda, K., Nakata, H., Nakayama, S., and Ishizuka, M. (2020). Detoxification of lead-bearing zinc plant leach residues from Kabwe, Zambia by coupled extraction-cementation method. Journal of Environmental Chemical Engineering, 8, 104197. https://doi.org/10.1016/j.jece.2020.104197
  • [22] Gammons, C.H. and Williams-Tones, A.E. (1995). The solubility of Au-Ag alloy + AgCl in HCl/NaCl solutions at 300°C: new data on the stability of Au (1) chloride complexes in hydrothermal fluids. Geochimica et Cosmochimica Acta, 59, 3453–3468. https://doi.org/10.1016/0016-7037(95)00234-Q
  • [23] Tagirov, B.R., Zotov, A. V., and Akinfiev, N.N. (1997). Experimental study of dissociation of HCl from 350 to 500°C and from 500 to 2500 bars: thermodynamic properties of HCl°(aq). Geochimica et Cosmochimica Acta, 61, 4267–4280. https://doi.org/10.1016/S0016-7037(97)00274-3
  • [24] Bahram, B. and Javad, M. (2011). Chloride leaching of lead and silver from refractory zinc plant residue. Research Journal of Chemistry and Environment, 15, 1–8.
  • [25] Raghavan, R., Mohanan, P.K., and Patnaik, S.C. (1998). Innovative processing technique to produce zinc concentrate from zinc leach residue with simultaneous recovery of lead and silver. Hydrometallurgy, 48, 225–237. https://doi.org/10.1016/S0304-386X(97)00082-0
  • [26] Raghavan, R., Mohanan, P.K., and Swarnkar, S.R. (2000). Hydrometallurgical processing of lead-bearing materials for the recovery of lead and silver as lead concentrate and lead metal. Hydrometallurgy, 58, 103–116. http,s://doi.org/10.1016/S0304-386X(00)00108-0
  • [27] Zárate-gutiérrez, R., Lapidus, G.T., and Morales, R.D. (2010). Hydrometallurgy pressure leaching of a lead–zinc–silver concentrate with nitric acid at moderate temperatures between 130 and 170 °C. Hydrometallurgy, 104, 8–13. https://doi.org/10.1016/j.hydromet.2010.04.001
  • [28] Basir, S.M.A. and Rabah, M.A. (1999). Hydrometallurgical recovery of metal values from brass melting slag. Hydrometallurgy, 53, 31–44.
  • [29] Liu, Q., Zhao, Y., and Zhao, G. (2011). Production of zinc and lead concentrates from lean oxidized zinc ores by alkaline leaching followed by two-step precipitation using sulfides. Hydrometallurgy, 110, 79–84. https://doi.org/10.1016/J.HYDROMET.2011.08.009
  • [30] Jiang, G., Peng, B., Liang, Y., Chai, L., Wang, Q., Li, Q., and Hu, M. (2017). Recovery of valuable metals from zinc leaching residue by sulfate roasting and water leaching. Transactions of Nonferrous Metals Society of China (English edition), 27, 1180–1187. https://doi.org/10.1016/S1003-6326(17)60138-9
  • [31] Yoğurtcuoğlu, E. (2022). Evaluation of flotation wastes of oxidised ores (in Turkish). IV International Turkic World Congress on Science and Engineering (TURK-COSE), 1098–1104.
  • [32] Ju, S., Motang, T., Shenghai, Y., and Yingnian, L. (2005). Dissolution kinetics of smithsonite ore in ammonium chloride solution. Hydrometallurgy, 80, 67–74. https://doi.org/10.1016/j.hydromet.2005.07.003
  • [33] Chen, A., Zhao, Z. W., Jia, X., Long, S., Huo, G., and Chen, X. (2009). Alkaline leaching Zn and its concomitant metals from refractory hemimorphite zinc oxide ore. Hydrometallurgy, 97, 228–232. https://doi.org/10.1016/j.hydromet.2009.01.005
  • [34] Dou, A.C., Yang, T.Z., Yang, J.X., Wu, J.H., and Wang, A. (2011). Leaching of low grade zinc oxide ores in Ida2-- H2O system. Transactions of Nonferrous Metals Society of China (English edition), 21, 2548–2553. https://doi.org/10.1016/S1003-6326(11)61049-2
  • [35] Irannajad, M., Meshkini, M., and Azadmehr, A.R. (2013). Leaching of zinc from low grade oxide ore using organic acid. Physicochemical Problems of Mineral Processing, 49, 547–555. https://doi.org/10.5277/ppmp130215
  • [36] Güler, E., Seyrankaya, A., and Cöcen, I. (2011). Hydrometallurgical evaluation of zinc leach plant residue. Asian Journal of Chemistry, 23, 2879–2888.
  • [37] Yoğurtcuoğlu, E. (2022). Usage of acetic acid for boric acid production from boron wastes. Niğde Ömer Halisdemir University Journal of Engineering Sciences, 11, 819–825. https://doi.org/10.28948/ngmuh.
  • [38] Yoğurtcuoğlu, E. (2022). The citric acid leaching of boron process wastes (early access). Canadian Metallurgical Quarterly, 1–18. https://doi.org/10.1080/00084433.2022.2131132
There are 38 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Research Articles
Authors

Emine Yoğurtcuoğlu 0000-0002-9961-8809

Publication Date June 30, 2023
Submission Date January 27, 2023
Published in Issue Year 2023 Issue: 053

Cite

IEEE E. Yoğurtcuoğlu, “MULTI-METAL RECOVERY FROM FLOTATION TAILINGS WITH CITRIC ACID ON THE NACl MEDIA”, JSR-A, no. 053, pp. 59–73, June 2023, doi: 10.59313/jsr-a.1243469.