Research Article
BibTex RIS Cite

3-Pikolin ve Diklofenak İçeren Yeni Diklofenak Kompleksinin Sentezi, Kristal, Spektroskopik, Termik ve DFT Çalışmaları

Year 2019, Volume: 12 Issue: 2, 966 - 979, 31.08.2019
https://doi.org/10.18185/erzifbed.527155

Abstract

[PdCl2(3-pic)2] kompleksi
kullanılarak, 3-pikolin ve diklofenak ligandları içeren yeni bir palladyum(II)
kompleksi sentezlendi. Sentezlenen kompleks, elementel, termik ve spektroskopik
yöntemler ile karakterize edildi. X-Işını tek kristal analizi, kompleksin kare
düzlem geometriye sahip olduğunu ve bileşiğinin formülünün
[Pd(dicl)2(3-pic)2] olduğunu doğrulamaktadır.
Kompleksin elektronik özellikleri, doğal bağ orbital (NBO) popülasyon
analiziyle araştırılmıştır. Ayrıca, [Pd(dicl)2(3-pic)2]
kompleksi, [PdCl2(3-pic)2] kompleksinden
sentezlendiğinden ötürü; komplekslerin bağıl kararlılıkları, DFT hesaplamalarında
elde edilen teorik bulgularla karşılaştırılmıştır. Termik analiz tekniği,
kompleksin 200 oC'ye kadar kararlı olduğunu göstermektedir.

References

  • Al-Allaf, T.A.K., Ayoub, M.T., Rashan, L.J. 1990. Synthesis and characterization of novel biologically active platinum(II) and palladium(II) complexes of some β-carboline alkaloids. J. Inorg. Biochem., 38, 47-56.
  • Anacona, J.R., Bastardo, E. 1999. Manganese(II) and palladium(II) complexes containing a new macrocyclic Schiff base ligand: antibacterial properties. Transition Met. Chem., 24, 478-480.
  • APEX2. 2013. Bruker AXS Inc. Madison Wisconsin USA.
  • Beck, A., Krischak, G., Sorg, T., Augat, P., Farker, K., Merkel, U., Kinzl, L., Claes, L. 2013. Influence of diclofenac (group of nonsteroidal anti-inflammatory drugs) on fracture healing. Arch Orthop Trauma Su, 123, 327-332.
  • Caglar, S., Aydemir, I.E., Adıgüzel, E., Caglar, B., Demir, S., Buyukgungor, O. 2013. Four copper (II) diclofenac complexes with pyridine derivatives: Synthesis, crystal structures, spectroscopic properties, thermal analysis and catechol oxidase activities. Inorg. Chim. Acta, 408, 131-138.
  • Caglar, S., Aydemir, I.E., Cankaya, M., Kuzucu, M., Temel, E., Buyukgungor, O. 2014. Four diclofenac complexes with cobalt(II) and nickel(II) ions: synthesis, spectroscopic properties, thermal decompositions, crystal structures, and carbonic anhydrase activities. J. Coord. Chem., 67, 969-985.
  • Carvalho, M.A., Souza, B.C., Paiva, R.E.F., Bergamini, F.R.G., Gomes, A.F., Gozzo, F.C. 2015. Synthesis and crystal structure of a palladium (II) complex with the amino acid L-citrulline. Powder Diffr., 30, 357-361.
  • Castellari, C., Feroci, G., Ottani, S. 1999. Diclofenac interactions: tetrakis[[]-2-(2,6-dichloroanilino)phenylacetato]-1:2[қ]8O:O'-diacetone-1[қ]O,2[қ]O-dicopper(II)(Cu--Cu) acetaldehyde solvate. Acta Crystallogr. Sect. C, 55, 907-910.
  • Chan, W.T.K., Wong, W.T. 2013. A brief introduction to transition metals in unusual oxidation states. W.T. Polyhedron, 52, 43-61.
  • Chen, W., Liu, C.M., Xiong, R.G., You, X.Z. 1997. 4:1 Lewis Base Adducts of Palladium Dichloride: [Pd(3-picoline)4]Cl2.2H2O. Acta Crystallogr. Sect. C, 53, 1218-1220.
  • Dimiza, F., Perdih, F., Tangoulis, V., Turel, I., Kessissoglou, D.P., Psomas, G. 2011. Interaction of copper (II) with the non-steroidal anti-inflammatory drugs naproxen and diclofenac: Synthesis, structure, DNA-and albumin-binding. J. Inorg. Biochem., 105, 476-489.
  • Etcheverry, S.B., Barrio, D.A., Cortizo, A.M., Williams, P.A.M. 2002. Three new vanadyl (IV) complexes with non-steroidal anti-inflammatory drugs (Ibuprofen, Naproxen and Tolmetin). Bioactivity on osteoblast-like cells in culture. J. Inorg. Biochem., 88, 94-100.
  • Farrugia, L.J. 1999. WinGX suite for small-molecule single-crystal crystallography. Apply Cryst., 32, 837-838.
  • Frisch, M. J., Trucks, G.W., Schlegel, H. B., Scuseria, G. E., Robb, M. A., Cheeseman, J. R., Scalmani, G., Barone, V., Mennucci, B., Petersson, G. A., Nakatsuji, H., Caricato, M., Li, X., Hratchian, H. P., Izmaylov, A. F., Bloino, J., Zheng, G., Sonnenberg, J. L., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Montgomery, Jr J. A., Peralta, J. E., Ogliaro, F., Bearpark, M., Heyd, J. J., Brothers, E., Kudin, K. N., Staroverov, V. N., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J C., Iyengar, SS., Tomasi, J., Cossi, M., Rega, N., Millam, J. M., Klene, M.; Knox, J. E., JBCross, Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R. E.; Yazyev, O.; Austin, A. J., Cammi, R., Pomelli, C., Ochterski, J. W., Martin, R. L., Morokuma, K., Zakrzewski, V. G., Voth, G, A., Salvador, P., Dannenberg, J. J., Dapprich, S., Daniels, A. D., Farkas, Ö., Foresman, J. B., Ortiz, J. V., Cioslowski, J., and Fox, D. J. 2009. Gaussian 09, Revision A.1, Gaussian, Inc.: Wallingford CT.
  • Garoufis, A., Hadjikakou, S.K., Hadjiliadis, N. 2009. Palladium coordination compounds as anti-viral, anti-fungal, anti-microbial and anti-tumor agents. Coord. Chem. Rev., 253, 1384-1397.
  • Hallıgudı, S.B., Bhatt, K.N., Khan, N.H., Kurashy, R.I., Venkatsubramanıan, K. 1996. Synthesis, structural characterization and catalytic carbonylation of nitrobenzene and amines by mononuclear palladium(II) complexes containing substituted pyridine ligands. Polyhedron, 15, 2093-2101.
  • Housby, J.N., Cahill, C.M., Chu, B., Prevelige, R., Bickford, K., Stevenson, M.A., Calderwood, S.K. 1999. Non-steroidal anti-inflammatory drugs inhibit the expression of cytokines and induce HSP70 in human monocytes. Cytokine, 11, 347-358.
  • Jain, V.K., Jain, L. 2005. The chemistry of binuclear palladium(II) and platinum(II) complexes,Coord. Chem. Rev., 249, 3075-3197.
  • Kalevaru,V.N., Raju, B.D., Rao, V.V., Martin, A. 2009. Preparation, characterisation and catalytic evaluation of MgF2 supported V2O5 catalysts for ammoxidation of 3-picoline. Appl. Catal. 352, 223-233.
  • Konstandinidou, M., Kourounakis, A., Yiangou, M., Hadjipetrou, L., Kovala-Demertzi, D., Hadjikakou, S., Demertzis, M. 1998. Anti-inflammatory properties of diclofenac transition metalloelement complexes. J. Inorg. Biochem., 70, 63-69.
  • Kourkoumelis, N., Demertzis, M.A., Kovala-Demertzi, D., Koutsodimou, A. Moukarika, A. 2004. Preparations and spectroscopic studies of organotin complexes of diclofenac. Spectrochim. Acta Part A, 60, 2253-2259.
  • Kovala-Demertzi, D., Mentzafos, D., Terzis, A. 1993. Metal complexes of the anti-inflammatory drug sodium [2-[(2,6-dichlorophenyl)amino]phenyl]acetate (diclofenac sodium). Molecular and crystal structure of cadmium diclofenac. Polyhedron, 12, 1361-1370.
  • Kovala-Demertzi, D., Theodorou, A., Demertzis, M.A., Raptopoulou, C.P., Terzis, A. 1997. Synthesis and characterization of tetrakis-μ-2-[(2,6dichlorophenyl) amino] benzeneacetodiaquodicopper(II) dihydrate and tetrakis-μ-2-[(2,6dichlorophenyl)amino]benzeneaceto dimethylformamidodicopper(II). J. Inorg. Biochem., 65, 151-157.
  • Kyropoulou, M., Raptopoulou, C.P., Psycharis,V., Psomas, G. 2013. Ni (II) complexes with non-steroidal anti-inflammatory drug diclofenac: Structure and interaction with DNA and albumins. Polyhedron, 61, 126-136.
  • Lai, S.W. Cheung, T.C., Chan, M.C.W., Cheung, K.K., Peng, S.M., Che, C.M.2000. Luminescent mononuclear and binuclear cyclometalated palladium(II) complexes of 6-Phenyl-2,2′-bipyridines: spectroscopic and structural comparisons with platinum(II) analogues 1,2. Inorg. Chem., 39, 255-262.
  • Lustri, W.R., Formiga, A.L.B., Rigatto, G., Corbi, P.P. 2012. Synthesis, spectroscopic characterization, DFT studies, and initial antibacterial assays in vitro of a new palladium(II) complex with tryptophan. J. Coord. Chem., 65, 1700-1711.
  • Ma, D.Y., Zhang, L.X., Rao, X.Y., Wu, T.L., Li, D.H., Xie, X.Q. 2013. Synthesis, characterization, luminescence, antibacterial, and catalytic activities of a palladium(II) complex involving a Schiff base. J. Coord. Chem., 66, 1486-1496.
  • Martin, A., Janke,C., Kalevaru,V.N. 2010. Ammoxidation of 3-picoline to nicotinonitrile over VPO catalysts. Appl. Catal., 376, 13-18.
  • Mercury, version 3.3; CCDC, available online via ccdc.cam.ac.uk/products/mercury.
  • Milani, B., Scarel, A., Zangrando, E., Mestroni, G., Carfagna,C., Binotti. B. 2003. Cationic palladium complexes with mono- and bidentate nitrogen-donor ligands: synthesis, characterization and reactivity in CO/styrene copolymerization reaction. Inorg. Chim. Acta, 350, 592-602.
  • Misaki, Y., Tani, Y., Taniguchi, M., Maitani, T., Tanaka, K., Bechgaard, K. 2000. Preparation and Properties of Gold Complexes with TTF Dithiolato Ligands. Mol. Cryst .Liq. Cryst., 343, 59-64.
  • Moro, A.C., Urbaczek, A.C., De Almeida, E.T., Pavan, F.R., Leite, C.Q.F., Netto, A.V.G., Mauro, A.E. 2012. Binuclear cyclopalladated compounds with antitubercular activity: synthesis and characterization of [{Pd(C2,N-dmba)(X)}2(μ-bpp)]. J. Coord. Chem., 65, 1434-1442.
  • Njogu, E.M., Omondi, B., Nyamori, V.O. 2015. Review: Multimetallic silver(I)-pyridinyl complexes: coordination of silver(I) and luminescence. J. Coord.Chem., 68, 3389-3431.
  • Patel, M.N., Dosi, P.A., Bhatt, B.S. 2012. Square planar palladium (II) complexes of bipyridines: synthesis, characterization, and biological studies. J. Coord. Chem., 65, 3833-3844.
  • Psomas, G., Kessissoglou, D.P. 2013. Quinolones and non-steroidal antiinflammatory drugs interacting with copper(II), nickel(II), cobalt(II) and zinc(II): Structural features, biological evaluation and perspectives. Dalton Trans, 42, 6252-6276.
  • Quirinia, A., Viidik, A. 1997. Diclofenac and indomethacin influence the healing of normal and ischemic incisional wounds in skin. J. Plast. Reconstr. Hand. Surg., 31, 213-219.
  • Romerosa, A., Bergamini, P., Bertolasi, V., Canella, A., Cattabriga, M., Gavioli, R., Mañas, S., Mantovani, N., Pellacani, L. 2004. Biologically active platinum complexes containing 8-thiotheophylline and 8-(methylthio) theophylline. Inorg. Chem., 43, 905-913.
  • Sheldrick, G.M. 2015. Crystal structure refinement with SHELXL. Acta Cryst. C, 71, 3-8.
  • Sheldrick, G.M.. 2008. A short history of SHELX.2008. Acta Cryst. A, 64, 112-122.
  • Srinivas, N., Radha Kishan, M., Kulkarni, S.J., Raghavan, K.V. 2000. Ammoxidation of picolines over modified silicoaluminophosphate molecular sieves. Microporous Mesoporous Mater., 39, 125-134.
  • Tessier, C., Rochon, F.D. 1999. Multinuclear NMR study and crystal structures of complexes of the types cis- and trans-Pt(Ypy)2X2, where Ypy=pyridine derivative and X=Cl and I. Inorg. Chim. Acta, 295, 25-38.
  • Tunçay, M., Çaliş, S., Kaş, H.S., Ercan, M.T., Peksoy, I., Hincal, A.A. 2000. Diclofenac sodium incorporated PLGA (50: 50) microspheres: formulation considerations and in vitro/in vivo evaluation. Int. J. Pharm., 195, 179-188.
  • Tzeng, B.C., Chan, S.C., Chan, M.C.W. Che, C.M., Cheung, K.K., Peng, S.M.2001. Palladium(II) and platinum(II) analogues of luminescent diimine triangulo complexes supported by triply bridging sulfide ligands: structural and spectroscopic comparisons. Inorg. Chem., 40, 6699-6704.
  • Wang, Z., Cohen, S.M. 2009. Postsynthetic modification of metal-organic frameworks Chem. Soc. Rev., 38, 1315-1329.
  • Zampakou, M., Hatzidimitriou, A.G., Papadopoulos, A.N., Psomas, G. 2015. Neutral and cationic manganese (II)-diclofenac complexes: structure and biological evaluation. J. Coord. Chem., 68, 4355-4372.
  • Zhang, J.P., Huang, X.C., Chen, X.M. 2009. Supramolecular isomerism in coordination polymers. Chem. Soc. Rev., 38, 2385-2396.

A New Palladium(II) Complex With 3-Picoline and Diclofenac: Synthesis, Crystal, Spectroscopic, Thermal and DFT Studies

Year 2019, Volume: 12 Issue: 2, 966 - 979, 31.08.2019
https://doi.org/10.18185/erzifbed.527155

Abstract

A novel
palladium(II) complex with 3-picoline and diclofenac ligands was synthesized
using [PdCl2(3-pic)2] as the precursor. The synthesized complex is
characterized by elemental and thermal and spectroscopic methods. Single X-Ray
analysis confirms that the complex has square plane geometry and the compound
of formula is [Pd(dicl)2(3-pic)2]. Electronic properties
of the complex have been probed by natural bond orbital (NBO) population
analyses. Furthermore, relative stabilities of the complexes have been also
compared in theoretical insight based on DFT computations since complex [PdCl2(3-pic)2]
is the precursor of [Pd(dicl)2(3-pic)2]. Thermal analysis
shows that the complex is stable up to 200 oC.

References

  • Al-Allaf, T.A.K., Ayoub, M.T., Rashan, L.J. 1990. Synthesis and characterization of novel biologically active platinum(II) and palladium(II) complexes of some β-carboline alkaloids. J. Inorg. Biochem., 38, 47-56.
  • Anacona, J.R., Bastardo, E. 1999. Manganese(II) and palladium(II) complexes containing a new macrocyclic Schiff base ligand: antibacterial properties. Transition Met. Chem., 24, 478-480.
  • APEX2. 2013. Bruker AXS Inc. Madison Wisconsin USA.
  • Beck, A., Krischak, G., Sorg, T., Augat, P., Farker, K., Merkel, U., Kinzl, L., Claes, L. 2013. Influence of diclofenac (group of nonsteroidal anti-inflammatory drugs) on fracture healing. Arch Orthop Trauma Su, 123, 327-332.
  • Caglar, S., Aydemir, I.E., Adıgüzel, E., Caglar, B., Demir, S., Buyukgungor, O. 2013. Four copper (II) diclofenac complexes with pyridine derivatives: Synthesis, crystal structures, spectroscopic properties, thermal analysis and catechol oxidase activities. Inorg. Chim. Acta, 408, 131-138.
  • Caglar, S., Aydemir, I.E., Cankaya, M., Kuzucu, M., Temel, E., Buyukgungor, O. 2014. Four diclofenac complexes with cobalt(II) and nickel(II) ions: synthesis, spectroscopic properties, thermal decompositions, crystal structures, and carbonic anhydrase activities. J. Coord. Chem., 67, 969-985.
  • Carvalho, M.A., Souza, B.C., Paiva, R.E.F., Bergamini, F.R.G., Gomes, A.F., Gozzo, F.C. 2015. Synthesis and crystal structure of a palladium (II) complex with the amino acid L-citrulline. Powder Diffr., 30, 357-361.
  • Castellari, C., Feroci, G., Ottani, S. 1999. Diclofenac interactions: tetrakis[[]-2-(2,6-dichloroanilino)phenylacetato]-1:2[қ]8O:O'-diacetone-1[қ]O,2[қ]O-dicopper(II)(Cu--Cu) acetaldehyde solvate. Acta Crystallogr. Sect. C, 55, 907-910.
  • Chan, W.T.K., Wong, W.T. 2013. A brief introduction to transition metals in unusual oxidation states. W.T. Polyhedron, 52, 43-61.
  • Chen, W., Liu, C.M., Xiong, R.G., You, X.Z. 1997. 4:1 Lewis Base Adducts of Palladium Dichloride: [Pd(3-picoline)4]Cl2.2H2O. Acta Crystallogr. Sect. C, 53, 1218-1220.
  • Dimiza, F., Perdih, F., Tangoulis, V., Turel, I., Kessissoglou, D.P., Psomas, G. 2011. Interaction of copper (II) with the non-steroidal anti-inflammatory drugs naproxen and diclofenac: Synthesis, structure, DNA-and albumin-binding. J. Inorg. Biochem., 105, 476-489.
  • Etcheverry, S.B., Barrio, D.A., Cortizo, A.M., Williams, P.A.M. 2002. Three new vanadyl (IV) complexes with non-steroidal anti-inflammatory drugs (Ibuprofen, Naproxen and Tolmetin). Bioactivity on osteoblast-like cells in culture. J. Inorg. Biochem., 88, 94-100.
  • Farrugia, L.J. 1999. WinGX suite for small-molecule single-crystal crystallography. Apply Cryst., 32, 837-838.
  • Frisch, M. J., Trucks, G.W., Schlegel, H. B., Scuseria, G. E., Robb, M. A., Cheeseman, J. R., Scalmani, G., Barone, V., Mennucci, B., Petersson, G. A., Nakatsuji, H., Caricato, M., Li, X., Hratchian, H. P., Izmaylov, A. F., Bloino, J., Zheng, G., Sonnenberg, J. L., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Montgomery, Jr J. A., Peralta, J. E., Ogliaro, F., Bearpark, M., Heyd, J. J., Brothers, E., Kudin, K. N., Staroverov, V. N., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J C., Iyengar, SS., Tomasi, J., Cossi, M., Rega, N., Millam, J. M., Klene, M.; Knox, J. E., JBCross, Bakken, V., Adamo, C., Jaramillo, J., Gomperts, R., Stratmann, R. E.; Yazyev, O.; Austin, A. J., Cammi, R., Pomelli, C., Ochterski, J. W., Martin, R. L., Morokuma, K., Zakrzewski, V. G., Voth, G, A., Salvador, P., Dannenberg, J. J., Dapprich, S., Daniels, A. D., Farkas, Ö., Foresman, J. B., Ortiz, J. V., Cioslowski, J., and Fox, D. J. 2009. Gaussian 09, Revision A.1, Gaussian, Inc.: Wallingford CT.
  • Garoufis, A., Hadjikakou, S.K., Hadjiliadis, N. 2009. Palladium coordination compounds as anti-viral, anti-fungal, anti-microbial and anti-tumor agents. Coord. Chem. Rev., 253, 1384-1397.
  • Hallıgudı, S.B., Bhatt, K.N., Khan, N.H., Kurashy, R.I., Venkatsubramanıan, K. 1996. Synthesis, structural characterization and catalytic carbonylation of nitrobenzene and amines by mononuclear palladium(II) complexes containing substituted pyridine ligands. Polyhedron, 15, 2093-2101.
  • Housby, J.N., Cahill, C.M., Chu, B., Prevelige, R., Bickford, K., Stevenson, M.A., Calderwood, S.K. 1999. Non-steroidal anti-inflammatory drugs inhibit the expression of cytokines and induce HSP70 in human monocytes. Cytokine, 11, 347-358.
  • Jain, V.K., Jain, L. 2005. The chemistry of binuclear palladium(II) and platinum(II) complexes,Coord. Chem. Rev., 249, 3075-3197.
  • Kalevaru,V.N., Raju, B.D., Rao, V.V., Martin, A. 2009. Preparation, characterisation and catalytic evaluation of MgF2 supported V2O5 catalysts for ammoxidation of 3-picoline. Appl. Catal. 352, 223-233.
  • Konstandinidou, M., Kourounakis, A., Yiangou, M., Hadjipetrou, L., Kovala-Demertzi, D., Hadjikakou, S., Demertzis, M. 1998. Anti-inflammatory properties of diclofenac transition metalloelement complexes. J. Inorg. Biochem., 70, 63-69.
  • Kourkoumelis, N., Demertzis, M.A., Kovala-Demertzi, D., Koutsodimou, A. Moukarika, A. 2004. Preparations and spectroscopic studies of organotin complexes of diclofenac. Spectrochim. Acta Part A, 60, 2253-2259.
  • Kovala-Demertzi, D., Mentzafos, D., Terzis, A. 1993. Metal complexes of the anti-inflammatory drug sodium [2-[(2,6-dichlorophenyl)amino]phenyl]acetate (diclofenac sodium). Molecular and crystal structure of cadmium diclofenac. Polyhedron, 12, 1361-1370.
  • Kovala-Demertzi, D., Theodorou, A., Demertzis, M.A., Raptopoulou, C.P., Terzis, A. 1997. Synthesis and characterization of tetrakis-μ-2-[(2,6dichlorophenyl) amino] benzeneacetodiaquodicopper(II) dihydrate and tetrakis-μ-2-[(2,6dichlorophenyl)amino]benzeneaceto dimethylformamidodicopper(II). J. Inorg. Biochem., 65, 151-157.
  • Kyropoulou, M., Raptopoulou, C.P., Psycharis,V., Psomas, G. 2013. Ni (II) complexes with non-steroidal anti-inflammatory drug diclofenac: Structure and interaction with DNA and albumins. Polyhedron, 61, 126-136.
  • Lai, S.W. Cheung, T.C., Chan, M.C.W., Cheung, K.K., Peng, S.M., Che, C.M.2000. Luminescent mononuclear and binuclear cyclometalated palladium(II) complexes of 6-Phenyl-2,2′-bipyridines: spectroscopic and structural comparisons with platinum(II) analogues 1,2. Inorg. Chem., 39, 255-262.
  • Lustri, W.R., Formiga, A.L.B., Rigatto, G., Corbi, P.P. 2012. Synthesis, spectroscopic characterization, DFT studies, and initial antibacterial assays in vitro of a new palladium(II) complex with tryptophan. J. Coord. Chem., 65, 1700-1711.
  • Ma, D.Y., Zhang, L.X., Rao, X.Y., Wu, T.L., Li, D.H., Xie, X.Q. 2013. Synthesis, characterization, luminescence, antibacterial, and catalytic activities of a palladium(II) complex involving a Schiff base. J. Coord. Chem., 66, 1486-1496.
  • Martin, A., Janke,C., Kalevaru,V.N. 2010. Ammoxidation of 3-picoline to nicotinonitrile over VPO catalysts. Appl. Catal., 376, 13-18.
  • Mercury, version 3.3; CCDC, available online via ccdc.cam.ac.uk/products/mercury.
  • Milani, B., Scarel, A., Zangrando, E., Mestroni, G., Carfagna,C., Binotti. B. 2003. Cationic palladium complexes with mono- and bidentate nitrogen-donor ligands: synthesis, characterization and reactivity in CO/styrene copolymerization reaction. Inorg. Chim. Acta, 350, 592-602.
  • Misaki, Y., Tani, Y., Taniguchi, M., Maitani, T., Tanaka, K., Bechgaard, K. 2000. Preparation and Properties of Gold Complexes with TTF Dithiolato Ligands. Mol. Cryst .Liq. Cryst., 343, 59-64.
  • Moro, A.C., Urbaczek, A.C., De Almeida, E.T., Pavan, F.R., Leite, C.Q.F., Netto, A.V.G., Mauro, A.E. 2012. Binuclear cyclopalladated compounds with antitubercular activity: synthesis and characterization of [{Pd(C2,N-dmba)(X)}2(μ-bpp)]. J. Coord. Chem., 65, 1434-1442.
  • Njogu, E.M., Omondi, B., Nyamori, V.O. 2015. Review: Multimetallic silver(I)-pyridinyl complexes: coordination of silver(I) and luminescence. J. Coord.Chem., 68, 3389-3431.
  • Patel, M.N., Dosi, P.A., Bhatt, B.S. 2012. Square planar palladium (II) complexes of bipyridines: synthesis, characterization, and biological studies. J. Coord. Chem., 65, 3833-3844.
  • Psomas, G., Kessissoglou, D.P. 2013. Quinolones and non-steroidal antiinflammatory drugs interacting with copper(II), nickel(II), cobalt(II) and zinc(II): Structural features, biological evaluation and perspectives. Dalton Trans, 42, 6252-6276.
  • Quirinia, A., Viidik, A. 1997. Diclofenac and indomethacin influence the healing of normal and ischemic incisional wounds in skin. J. Plast. Reconstr. Hand. Surg., 31, 213-219.
  • Romerosa, A., Bergamini, P., Bertolasi, V., Canella, A., Cattabriga, M., Gavioli, R., Mañas, S., Mantovani, N., Pellacani, L. 2004. Biologically active platinum complexes containing 8-thiotheophylline and 8-(methylthio) theophylline. Inorg. Chem., 43, 905-913.
  • Sheldrick, G.M. 2015. Crystal structure refinement with SHELXL. Acta Cryst. C, 71, 3-8.
  • Sheldrick, G.M.. 2008. A short history of SHELX.2008. Acta Cryst. A, 64, 112-122.
  • Srinivas, N., Radha Kishan, M., Kulkarni, S.J., Raghavan, K.V. 2000. Ammoxidation of picolines over modified silicoaluminophosphate molecular sieves. Microporous Mesoporous Mater., 39, 125-134.
  • Tessier, C., Rochon, F.D. 1999. Multinuclear NMR study and crystal structures of complexes of the types cis- and trans-Pt(Ypy)2X2, where Ypy=pyridine derivative and X=Cl and I. Inorg. Chim. Acta, 295, 25-38.
  • Tunçay, M., Çaliş, S., Kaş, H.S., Ercan, M.T., Peksoy, I., Hincal, A.A. 2000. Diclofenac sodium incorporated PLGA (50: 50) microspheres: formulation considerations and in vitro/in vivo evaluation. Int. J. Pharm., 195, 179-188.
  • Tzeng, B.C., Chan, S.C., Chan, M.C.W. Che, C.M., Cheung, K.K., Peng, S.M.2001. Palladium(II) and platinum(II) analogues of luminescent diimine triangulo complexes supported by triply bridging sulfide ligands: structural and spectroscopic comparisons. Inorg. Chem., 40, 6699-6704.
  • Wang, Z., Cohen, S.M. 2009. Postsynthetic modification of metal-organic frameworks Chem. Soc. Rev., 38, 1315-1329.
  • Zampakou, M., Hatzidimitriou, A.G., Papadopoulos, A.N., Psomas, G. 2015. Neutral and cationic manganese (II)-diclofenac complexes: structure and biological evaluation. J. Coord. Chem., 68, 4355-4372.
  • Zhang, J.P., Huang, X.C., Chen, X.M. 2009. Supramolecular isomerism in coordination polymers. Chem. Soc. Rev., 38, 2385-2396.
There are 46 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Makaleler
Authors

Sema Çağlar

Serkan Demir

Publication Date August 31, 2019
Published in Issue Year 2019 Volume: 12 Issue: 2

Cite

APA Çağlar, S., & Demir, S. (2019). A New Palladium(II) Complex With 3-Picoline and Diclofenac: Synthesis, Crystal, Spectroscopic, Thermal and DFT Studies. Erzincan University Journal of Science and Technology, 12(2), 966-979. https://doi.org/10.18185/erzifbed.527155