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Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey)

Year 2019, Volume: 158 Issue: 158, 141 - 164, 25.04.2019
https://doi.org/10.19111/bulletinofmre.461255

Abstract

Three different
types of hydrothermal alterations have occurred in the Eocene magmatics of the
northern part of Sivas-Turkey which include propylitic phyllic / sericitic and
argillic. Hydrothermal alteration affected both Karataş volcanites and Kösedağ
syenite. The clay formations are concentrated in two major zones; extending in
NE-SW direction and intersecting both plutonic and volcanic rocks with circular
opening cracks within the volcanics parallel to the plutonic-volcanic contact.
Hypogene and supergene hydrothermal alteration products occurring on surface
and/or near surface conditions represent the primary and secondary minerals
that develop directly and mostly from feldspars with the mechanisms of neoformation
and/or degradation. The hypogene minerals are formed in two stages of early
(kaolinite, pyrophyllite, illite, I-S (illite-smectite), smectite, quartz and
opal-CT) and late (barite, ore minerals, alunite, goyazite, jarosite, chlorite
and C-S). Tourmaline, epidote and carbonates (calcite, dolomite, azurite and malachite)
are considered as metasomatic and supergeneous minerals, respectively. The most
common mineral paragenesis are kaolinite + quartz + goethite + goyazite or
alunite, kaolinite + quartz + jarosite + feldspar ± goethite and/or goyazite in
the argillic alteration zone, I-S + quartz + jarosite ± goethite ± feldspar as
well as I-S + quartz + feldspar minerals in the sericitic alteration zone.
Kaolinite (T) is mostly in the form of pseudohexagonal platies, I-S (R1, R3 as
argillic alteration origins, 1Md, 2M1, 1M and R3 as sericitic alteration
origins) forming fi ber-acicular bundles parallel to each other.

References

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Year 2019, Volume: 158 Issue: 158, 141 - 164, 25.04.2019
https://doi.org/10.19111/bulletinofmre.461255

Abstract


References

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  • Ariana Z., Par W., Mario B., Vladimir M., 2016. Geological, mineralogical and chemical characterization of Devonian kaolinite-bearing sediments for further applications in the ceramic (tiles) industry in La Paz, Bolivia. Environ Earth Sci, 75:546, 1-15.
  • Arslan, M., Kadir, S., Abdioğlu, E., Kolayli, H., 2006. Origin and formation of kaolin minerals in saprolite of Tertiary alkaline volcanic rocks, Eastern Pontides, NE Turkey. Clay Minerals, 41(2), 597-617.
  • Başıbüyük, Z., 2006. Eosen volkaniklerinin hidrotermal alterasyon mineralojisi-petrografisi ve jeokimyası: Zara-İmranlı-Suşehri-Şerefiye Dörtgeni’nden bir örnek (Sivas Kuzeydoğusu, İç-Doğu Anadolu, Türkiye). Doktora Tezi, C.Ü. Fen Bil. Enst. Sivas, 269s.
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  • Berman R.G., 1988, Internally-consistent thermodynamic data for minerals in the system Na2O-K2O-CaO-MgO-FeO-Fe2O3-Al2O3-SiO2-TiO2-H2O-CO2: Journal of Petrology, v. 29, p. 445-522.
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  • Bohor, B.F. ve Triplehorn, D.M.,1993. Tonsteins: Altered volcanic ash layers in coal bearing sequences. Geological Society of America, Special Paper, 285, 44 pp.
  • Bozkaya, Ö., Yalçın, H., Başıbüyük, Z., Bozkaya, G., 2007. Metamorphic-hosted pyrophyllite and dickite occurrences from the hydrous Al-silicate deposits of the Malatya-Pütürge region, Central Eastern Anatolia, Turkey. Clays and Clay Minerals, 55, 4, p. 423-442.
  • Boztuğ, D., Jonckheere, R. C., 2007. Apatite fission track data from central Anatolian granitoids (Turkey): Constraints on Neo‐Tethyan closure. Tectonics, 26(3).
  • Boztuğ, D., Tichomirowa, M., Bombach, K. 2007. 207Pb/206Pb single-zircon evaporation ages of some granitoid rocks reveal continent-oceanic island arc collision during the Cretaceous geodynamic evolution of the central Anatolian crust, Turkey. Journal of Asian Earth Sciences, 31(1), 71-86.
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  • Brindley, G.W., Wardle R., 1970. Monoclinic and triclinic forms of pyrophyllite and pyrophyllite anhydride. Am. Miner., 48, 42-61.
  • Brown, G., Brindley, G.W., 1980. X-ray diffraction procedures for clay mineral identification. In Crystal Structuresof Clay Minerals ang their X-ray Identification, Mineralogical Society, London, 305-360.
  • Chagnon, A., Desjardins, M., 1991. Détermination de la composition de la chlorite par diffraction et microanalyse aux rayons X. Canadian Mineralogist, 29, 245-254.
  • Collins, D.R., Catlow, C.R.A., 1991. Energy-minimized hydrogen-atom positions of kaolinite. Acta Cryst., Vol.47, pp.678-682.
  • Cravero F., Marfil S. and Maiza P., 2010. Statistical analysis of geochemical data: A tool: to discriminate between kaolin deposits of hypogene and supergen origin. Patagonia, Argentina. Clay Minerals, 183-196.
  • Davies, J. H., Von Blanckenburg, F., 1995. Slab breakoff: a model of lithosphere detachment and its test in the magmatism and deformation of collisional orogens. Earth and Planetary Science Letters, 129(1), 85-102.
  • Domínguez E., Murray H.H., 1995. Genesis of the Chubut river valley kaolin deposits, and their industrial applications. Pp. 129-134 in: Proceedings of the 10th International Clay Conference, 1993 (G.J. Churchman, R.W. Fitzpatrick & R.A. Eggleton, editors) CSIRO Publishing, Melbourne, Australia.
  • Domínguez E., Murray, H.H., 1997. The Lote 8 Kaolin Deposit, Santa Cruz, Argentina. Genesis and paper industrial application. Pp. 57-64 in: Proceedings of the 11th International Clay Conference (H. Kodama, A.M. Mermut & J.K. Torrance, editors) Ottawa, Canada.
  • Duda, R., Rejl, L., 1990. Minerals of The World. Arch Cape Press, New York, 520 p.
  • Ece, O.I., Nakagawa, Z.-E., 2003. Alteration of volcanic rocks and genesis of kaolin deposits in the Şile region, northern İstanbul, Turkey. Part II: differantial mobility of elements. Clay Minerals, 38, p.529-550.
  • Ece, O.I., Nakagawa, Z.-E., Schroeder, P.A., 2003. Alteration of volcanic rocks and genesis of kaolin deposits in the Şile region, northern İstanbul, Turkey. I: Clay Mineralogy. Clays and Clay Minerals, Vol.51, No.6, p.675-688.
  • Ece Ö.I., Schroeder, P.A., 2007. Clay mineralogy and chemistry of halloysite and alunite deposits in the Turplu area, Balıkesir, Turkey. Clays and Clay Minerals, 55, 18-35.
  • Ece, Ö.I., Schroeder, P.A., Smilley, M., Wampler, M., 2008. Acid-sulfate alteration volcanic rocks and genesis of halloysite and alunite deposits in the Biga Peninsula, NW Turkey. Clay Minerals, 43, 281-315.
  • Ece, Ö.İ., Ekinci, B., Schroeder, P.A., Crowe, D., Esenli, F., 2013. Origin of the Düvertepe kaolin-alunite deposits in Simav Graben, Turkey: Timing and Styles of hydrothermal mineralization. Journal of Volcanology and Geothermal Research, 255, 57-18.
  • Efe, A., Gökçe, A., 1999. Maden köyü (İmranlı-Sivas) çevresindeki Pb-Zn yataklarının jeolojisi ve sıvı kapanım incelemeleri. C.Ü. Mühendislik Fakültesi Dergisi Seri A-Yerbilimleri, 16, 29-38.
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There are 70 citations in total.

Details

Primary Language English
Subjects Engineering
Journal Section Articles
Authors

Zeynel Başıbüyük 0000-0003-2845-148X

Hüseyin Yalçın 0000-0001-9539-2817

Publication Date April 25, 2019
Published in Issue Year 2019 Volume: 158 Issue: 158

Cite

APA Başıbüyük, Z., & Yalçın, H. (2019). Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey). Bulletin of the Mineral Research and Exploration, 158(158), 141-164. https://doi.org/10.19111/bulletinofmre.461255
AMA Başıbüyük Z, Yalçın H. Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey). Bull.Min.Res.Exp. April 2019;158(158):141-164. doi:10.19111/bulletinofmre.461255
Chicago Başıbüyük, Zeynel, and Hüseyin Yalçın. “Mineralogy, Petrography and Origin of Hydrothermal Alteration in Eocene Magmatites in Central Anatolia (Sivas-Turkey)”. Bulletin of the Mineral Research and Exploration 158, no. 158 (April 2019): 141-64. https://doi.org/10.19111/bulletinofmre.461255.
EndNote Başıbüyük Z, Yalçın H (April 1, 2019) Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey). Bulletin of the Mineral Research and Exploration 158 158 141–164.
IEEE Z. Başıbüyük and H. Yalçın, “Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey)”, Bull.Min.Res.Exp., vol. 158, no. 158, pp. 141–164, 2019, doi: 10.19111/bulletinofmre.461255.
ISNAD Başıbüyük, Zeynel - Yalçın, Hüseyin. “Mineralogy, Petrography and Origin of Hydrothermal Alteration in Eocene Magmatites in Central Anatolia (Sivas-Turkey)”. Bulletin of the Mineral Research and Exploration 158/158 (April 2019), 141-164. https://doi.org/10.19111/bulletinofmre.461255.
JAMA Başıbüyük Z, Yalçın H. Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey). Bull.Min.Res.Exp. 2019;158:141–164.
MLA Başıbüyük, Zeynel and Hüseyin Yalçın. “Mineralogy, Petrography and Origin of Hydrothermal Alteration in Eocene Magmatites in Central Anatolia (Sivas-Turkey)”. Bulletin of the Mineral Research and Exploration, vol. 158, no. 158, 2019, pp. 141-64, doi:10.19111/bulletinofmre.461255.
Vancouver Başıbüyük Z, Yalçın H. Mineralogy, petrography and origin of hydrothermal alteration in Eocene magmatites in Central Anatolia (Sivas-Turkey). Bull.Min.Res.Exp. 2019;158(158):141-64.

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